Coulometry

The limiting factor in the accuracy of many controlled-potential coulometric methods of analysis is the determination of charge. When using controlled-current coulometry accuracy is determined by the current efficiency, by the accuracy with which we can measure current and time, and by the accuracy of the end point. A coulometric titration of the protein is possible, however, if we use the oxidation or reduction of a mediator to produce a solution species that reacts with the protein.

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Thus, reducing a molecule of tetrachloropicolinic acid requires four electrons. To analyze a brass alloy, a 0.

Search the Dictionary for More Terms. Instrumentation A three-electrode potentiostat is used to set the potential in controlled-potential coulometry. When its electrolysis is complete, we can reduce dichloroacetate by adjusting the potential to a more negative potential.

Since mass transfer is so important the solution is stirred during a bulk electrolysis. A coulometric titration of the protein is possible, however, if we use the oxidation or reduction of a mediator to produce a solution species that reacts with the protein. Second, because it is relatively easy to measure a small quantity of charge, we can use a coulometric titration to determine an analyte whose concentration is too small for a conventional titration.

coulomtery Platinum is the working electrode of choice when we need to apply a positive potential. The other, called coulometric titration or amperostatic coulometrykeeps the current measured in amperes constant using an amperostat.

11.3: Coulometric Methods

It is used to find coulpmetry amount of water in substances such as buttersugarcheesepaperand petroleum. In controlled-potential coulometry, accuracy is determined by current efficiency and by the determination of charge.

We welcome suggested improvements to any of our articles. The resulting oxidation products, which form at the anode, flow to the right and may coulomerry as an oxidizing agent. The reaction involves converting solid iodine into hydrogen iodide in the presence of sulfur dioxide and water.

Sign up for our Demystified newsletter and get this free guide. The electrochemical cell consists of a Pt working electrode and a Pt counter electrode placed in separate cells connected by a porous glass disk. Is the platinum working electrode the cathode or the anode?

By using this site, you agree to the Terms of Use and Privacy Policy. Voltammetry and amperometry are covered in section 11D.

3. Coulometry - Pharmaceutical Analysis [Book]

Construct a titration curve of potential versus time and determine the time needed to reach the equivalence point. Knowing the total charge, we then use equation In this case the working electrode is weighed before beginning the electrolysis and reweighed when the electrolysis is complete.

This decreases the time needed to reach the titration's end point. Coumetry uses a constant current source to deliver a measured amount of charge.

This page was last edited on 3 Aprilat The integrated area under the curve, shown in blueis the total charge.

Coulometry | chemistry | cityofbolivar.info

The majority of controlled-potential coulometric analyses involve the determination of inorganic cations and anions, including trace metals and halides ions. Accuracy When using controlled-current coulometry accuracy is determined coulomery the current efficiency, by the accuracy with which we can measure current and time, and by the accuracy of the end point.

The total charge at the end of the electrolysis is read directly from a digital readout. Depending upon the analyte, the oxidizing agent or the reducing reagent is selectively delivered to the analytical solution. There are other similarities between controlled-current coulometry and titrimetry.

Coulometry in Analytical Chemistry

What is the value of n for this reduction reaction? There are two basic categories of coulometric techniques. Potentiostatic coulometry involves holding couulometry electric potential constant during the reaction using a potentiostat.

To obtain an coulomehry value for N Aall the current must be used to oxidize or reduce the analyte. By exhaustive we mean that the analyte is completely oxidized or reduced at the working electrode or that it reacts completely with a reagent generated at the working electrode.

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